pincer metal complexes

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Pincer Metal Complexes
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Publisher : Elsevier
Release Date :
ISBN 10 : 9780128220917
Pages : 270 pages
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Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems transforming hydrocarbons and their derivatives from an synthetic and mechanistic point of view. The success stories of pincer-metal systems are discussed, as well as current and future challenges. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. It is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. Covers applications of pincer-metal complexes in organic transformations Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations Features a discussion of pincer-metal complexes for dehydrogenation of functionalized hydrocarbons, and electro-catalytic transformations

Pincer Metal Complexes

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems transforming hydrocarbons and their derivatives from an synthetic and mechanistic point of view. The success stories of pincer-metal systems are discussed, as well as current and future challenges. In recent years there has been a surge

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The Chemistry of Pincer Compounds

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties.

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Organometallic Pincer Chemistry

Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J.

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The Privileged Pincer Metal Platform  Coordination Chemistry   Applications

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research,

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Pincer and Pincer Type Complexes

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various

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Pincer Compounds

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book

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Synthesis and Reactivity of Late Transition Metal Pincer Complexes

Download or read online Synthesis and Reactivity of Late Transition Metal Pincer Complexes written by Karena A. Smoll, published by Unknown which was released on 2018. Get Synthesis and Reactivity of Late Transition Metal Pincer Complexes Books now! Available in PDF, ePub and Kindle.

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Synthesis of Pincer type NHC Ligands with Phosphorus Functionalities and Their Ag I   Cu I  and Ir I III  Organometallic Complexes

Although the first metal complexes with the cyclometalated PCP pincer ligands (Figure 1a) were reported about 30 years ago, it is still a hot and fast developing topic covering all aspects of chemistry: mechanistic, structural, catalytic, synthetic, theoretical, and coordination studies. Pincer-based metal complexes possess a unique balance of stability and

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Metal Ligand Co operativity

Download or read online Metal Ligand Co operativity written by Gerard van Koten, published by Springer Nature which was released on . Get Metal Ligand Co operativity Books now! Available in PDF, ePub and Kindle.

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Bifunctional Molecular Catalysis

Masakatsu Shibasaki, Motomu Kanai, Shigeki Matsunaga, and Naoya Kumagai: Multimetallic Multifunctional Catalysts for Asymmetric Reactions.- Takao Ikariya: Bifunctional transition metal-based molecular catalysts for asymmetric syntheses.- Chidambaram Gunanathan and David Milstein: Bond Activation by Metal-Ligand Cooperation: Design of ”Green” Catalytic Reactions Based on Aromatization-Dearomatization of Pincer Complexes.- Madeleine

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Organotransition Metal Chemistry  From Bonding to Catalysis

Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last

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First Row Late D block Metal Pincer Complexes

Download or read online First Row Late D block Metal Pincer Complexes written by Jinting Xu, published by Unknown which was released on 2020. Get First Row Late D block Metal Pincer Complexes Books now! Available in PDF, ePub and Kindle.

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Enantioselective Organocatalysis

In this reference leaders at the forefront of research provide an insight into one of the hottest topics in organic synthesis, focusing on the most important enantioselective reactions. Clearly structured, each entry begins with a concise introduction, including a mechanistic discussion of the reaction, followed by preparative guidelines for newcomers,

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PNP Pincer Ligands in Late Transition Metal Nitrido Chemistry and Gold Catalysis

In this dissertation 1) an investigation of the possibility of forming cobalt- and nickel-nitrido complexes by studying the activation of the corresponding metal-azido complexes, and 2) an investigation into a novel, bimetallic approach to selectively promote the sigma,pi-activation mode in dual-gold Au(I) catalysis are presented. A diarylamine phosphine (PNP) pincer

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Manipulation of Carbon element Bonds by Pincer Ligated Iridium Complexes

"Since the seminal contributions of Moulton and Shaw in the 1970's, who synthesized the first "pincer" complexes, including tBu^PCPIrHCl (tBuPCP = k3-2,6-C6H3(CH2P(t^Bu)2)2), the chemistry of transition metal complexes ligated by tri-dentate, planar, pincer-type ligands has experienced vast development. Pincer-complexes of 1st, 2nd, and 3

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